Abstract

The title compound, C7H8NO2+·H2PO4−·H2O, is an ionic compound consisting of di­hydrogenmonophosphate anions, water mol­ecules and p-carboxy­phenyl­ammonium cations. The asymmetric unit contains two independent entities, i.e. 2(HOOC–C6H4–NH3+·H2PO4−·H2O). Anions and cations are linked to each other through strong hydrogen bonds, formed by all H atoms covalently bonded to anions, nitro­gen, carboxyl­ic groups and water mol­ecules. A three-dimensional complex network of hydrogen bonds ensures the cohesion of the ionic structure.

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