Abstract
The synthesis is simple, the structure very unusual. The [Pb18I44]8− ion (shown on the right), as a fraction of the NaCl structure type, is the largest iodoplumbate with discrete anions reported to date. The anion is obtained in the reaction of PbI2 with NaI in acetone as the tetrabutylammonium salt in the form of highly refractive, yellow octahedral crystals.
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More From: Angewandte Chemie International Edition in English
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