Abstract

The Pb-Pb age of phosphorite concretions of the Zigaza-Komarovo Formation, which composes the intermediate horizons of the Riphean stratotype of the South Urals, was determined in fractions resulting from the stepwise dissolution of concretions in 0.1 N, 0.5 N, and 1 N HCl. The determination of the Sr isotopic composition in phosphate fractions was favorable for rejection the fractions polluted with extraneous material. On the 207Pb/204Pb-206Pb/204Pb diagram, the isochron based on 31 points corresponds to 1330 ± 20 Ma (MSWD = 1.12), which is in agreement with the stratigraphic position of the Zigaza-Komarovo Formation. The decreased μ2 value of 9.57 for the phosphorite concretions relative to that of the average earthly lead based on the Stacey-Kramers model (9.74) is related to the rocks with an admixture of mantle lead, which occur in the run-off area of the Zigaza-Komarovo sediments.

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