Year-end Sale % OFF 
Abstract
Two chiral lead metal–organic nanotubes (CD-MONT-2 and CD-MONT-3) based on β-cyclodextrin (β-CD) and γ-cyclodextrin (γ-CD) were synthesized through a biphasic solvothermal reaction. The lead ions were connected by two β-CD or γ-CD molecules through their glycosidic oxygen atoms to generate a discrete metal–organic nanotube containing a {Pb14} or {Pb16} metallamacrocycle, respectively. Guest solvents of cyclohexanol molecules were trapped in the cavity of the β-CD-based nanotube, whereas there were no solvents in the cavity of the γ-CD-based nanotube. These differences directly led to the formation of different 3D packing structures. Their properties including temperature-dependent photoluminescence, adsorption of I2 molecules and thermal-decomposition behaviors were studied.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
