Pathways to sustainable methanol operations using gas-heated reforming (GHR) technologies

Abstract

The global methanol industry provides a unique supply chain to a plethora of chemicals and processes while also contributing to high quotas of greenhouse gas (GHG) emissions. Hence, as the world focuses on climate change mitigation, green technologies are emerging, allowing for low carbon operations. However, the timeliness and scalability of these technologies limit the sustainable transition of the current methanol industry. Thus, to promote low carbon operations within business-as-usual methanol production, innovative technologies need to be investigated-boasting high resource and energy efficiencies. Here, we examine the effectiveness of novel gas-heated reforming (GHR) over autothermal (ATR) and steam reforming (SMR)- coupled with carbon capture and storage platforms (CCS), in promoting sustainable methanol operations. Our results highlight the GHR as the most efficient flowsheet- with 11 % overall higher energy efficiency and 17 % increase in resource efficiency over ATR and SMR processes. Furthermore, through coupled CCS and electrification, energy and resource efficiencies were improved with GHR systems- achieving 14–41 % reduced GHG emissions compared to ATR and SMR flowsheets. Lastly, considering process economics, GHR flowsheets outperform- producing minimum selling prices up to 24 % lower than the current market. Ultimately, as the world seeks to promote a sustainable transition through the deployment of low carbon energy sources, GHR systems emerge as the preferred technologies- providing both economic and environmental benefits for future low carbon methanol operations.