Abstract
It remains challenging to elucidate the fundamental mechanisms behind the dynamic chirality inversion of supramolecular assemblies with pathway complexity. Herein, metal coordination driven assembly systems based on pyridyl-conjugated cholesterol (PVPCC) and metal ions (Ag+ or Al3+) are established to demonstrate pathway-directed, recyclable chirality inversion and assembly polymorphism. In the Ag(I)/PVPCC system, a competitive pathway leads Ag-Complex to form either kinetically controlled supramolecular polymer (Ag-SP I) or thermodynamically favored Ag-SP II, accompanied by reversible chiroptical inversion. Conversely, the Al(III)/PVPCC system displays a solvent-assisted consecutive pathway: the Al-Complex initially forms ethanol-containing Al-SP II, and subsequently converts into ethanol-free Al-SP I with opposite chiroptical performance upon thermal treatment. Moreover, stable chirality inversion in the solid state enables potential dynamic circularly polarized luminescence encryption when Ag(I)/PVPCC is co-assembled with thioflavin T. These findings provide the guidance for the dynamic modulation of chirality functionality in supramolecular materials for applications in information processing, data encryption, and chiral spintronics.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
