Abstract

The TNB alloy, a novel lightweight material, shows great potential for application in crucial aero-engine parts. This paper reveals the passive behavior of TNB alloy in electrochemical machining (ECM), Inconel 625 alloy was used for comparison. The polarization curve shows that TNB and Inconel 625 alloys have obvious passivation phenomenon at the passivation potential. Research reveals that the passive film structure of TNB alloy comprises a compact layer (about 7 nm) and a loose layer (about 13 nm), with significantly higher corrosion resistance in the compact layer compared to the loose layer. In contrast, the passive film structure of Inconel 625 alloy is a single layer with a thickness of approximately 11 nm. It was also found that the passive film composition for TNB alloy is TiO2, Al2O3, and Nb2O5. The composition of passive film for Inconel 625 alloy is NiO, Ni(OH)2, Cr2O3, MoO3, Nb2O5, FeO, and Fe2O3, and the content of Ni and Cr is high. TNB alloys exhibit uneven and loose lamellar morphology at low current densities, but can reach Ra 0.15 μm at greater than 15 A/cm2. There are always some disordered carbides rich in Nb and Mo on the surface of Inconel 625 alloy. Quantitative models were developed for both alloys to describe their electrochemical dissolution behavior.

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