Abstract

We investigated the passivation performance improvement of ultrathin Al2O3 tunnel oxide by chemical oxidation. The thickness of the Al2O3 tunnel oxide deposited by atomic layer deposition (ALD) was about 1 nm. The surface treatment was prepared as a function of chemical-oxidation time before ALD-Al2O3 growth. The Al2O3 films on surface-treated wafers showed improved passivation performance compared with the Al2O3 films on untreated wafers. The electrical characteristics showed that the surface-treated films, due to their enhanced initial ALD growth, enabled a low-interface-state defect and high film quality. In terms of tunneling and passivation performance, the optimal time of chemical oxidation was 2.5 min. The values of open-circuit voltage and carrier lifetime for the passivated tunnel oxide under this surface condition were 645 mV and 1 ms, respectively. A 1 nm ALD-Al2O3 films on surface treatment are applicable for passivated tunnel oxide.

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