Abstract
The reactions between 2-mercaptobenzothiazole (HMBT) and AgNO3 in ultrasonic bath with low and high concentrations of initial reagents provided yellow precipitates of [Ag6(MBT)6] (1), which can be considered as 1L and 1H, respectively. Powder XRD patterns of them showed that they have crystalline structure and SEM images of 1L and 1H approved that microblocks and nanosheets of 1 were formed, respectively. Similar studies after mechanical and thermo-mechanical treatment of 1L and 1H indicated that compound 1 with nanoparticle and agglomerated nanoparticle morphologies were obtained. As a result of heat and energy created from the friction process and also external heat source a roughening transition was occurred and the crystalline samples of 1L and 1H, loses their facets. This can be understood by considering compound 1 surface above the roughening temperature as a liquid surface.
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