Parylene nanocomposites using modified magnetic nanoparticles

Abstract

Parylene/Fe 3O 4 nanocomposites were synthesized and characterized. The nanocomposites were obtained by chemical vapour deposition polymerization of Parylene onto functionalized Fe 3O 4 nanoparticles. For this purpose, allyltrichlorosilane was used to modify the surface of 7 nm size Fe 3O 4 nanoparticles obtained by the coprecipitation method. The magnetic nanoparticles and obtained nanocomposite were characterized with X-ray diffraction (XRD), infrared spectroscopy (FTIR), thermal gravimetric analysis (TGA) and magnetic measurements (SQUID). The successful incorporation of different amounts of nanoparticles into Parylene was confirmed by FTIR and TGA. Interestingly, increments in saturation magnetization of the nanocomposites were observed ranging from 0 emu/g of neat Parylene to 16.94 emu/g in the case of nanocomposite films that contained 27.5 wt% of nanoparticles.