Abstract
Internal partition functions are calculated for nine molecules, which are abundant in the terrestrial atmosphere and are important in non-local thermodynamic equilibrium processes. Calculations are performed for the most abundant isotopomer and for several molecules for lesser abundant isotopomers as well. The temperature range considered in the study is for applications in the terrestrial atmosphere from 100 to 450 K . The resulting rotational and vibrational partition functions are each fit separately to a polynomial expression, which is third order in temperature. The methods of calculation of the partition functions, the convergence, and the quality of the fits for each isotopomer are discussed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Journal of Quantitative Spectroscopy and Radiative Transfer
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.