Abstract
A quaternary reciprocal system of fluorides, chlorides, and bromides of lithium and potassium was partitioned into simplexes by a geometric method and by a graph method. Phase transformations and chemical reactions in the boundary ternary reciprocal systems were described. A conversion line was experimentally studied, and information on crystallizing phases within the composition prism of the Li,K‖F,Cl,Br system was obtained and confirmed by X-ray powder diffraction data. An immiscibility region in the LiF-KCl-KBr stable triangle was outlined.
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