Abstract

AbstractIn spite of many additional complications, the extraction of complexes with inorganic ligands may be treated in the same way as the extraction of complexes with organic ligands. A general method of deducing the formula of the extracted species from studies of partition equilibria is outlined. Application of this method to the partition of tracer concentrations of the indium halide complexes indicates that a number of different species may be extracted. Although the hydrated acido‐complex, HInX4, aq, is the predominant species extracted from halogen acid solutions, significant proportions of the trihalide and complexes or ion‐pairs such as NaInX4 partition from halide media at relatively low acidities. The relative extractability of indium into a number of organic solvents follows the same general order for solutions in hydrochloric, hydrobromic and hydriodic acids.

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