Particulate contributions to light extinction and local forcing at a rural Illinois site

Abstract

The light extinction and direct forcing properties of the atmospheric aerosol were investigated for a midwestern rural site (Bondville, IL) using field measurements, a semi-empirical light extinction model, and a radiative transfer code. Model inputs were based on the site measurements of the physical and chemical characteristics of atmospheric aerosol during the spring, summer, fall and winter of 1994. The light scattering and extinction coefficients were calculated and apportioned using the elastic light scattering interactive efficiency (ELSIE) model (Sloane and Wolff, 1985, Atmospheric Environment 19(4), 669–680). The average efficiencies calculated for organic carbon (OC, carbon measured as organic multiplied by 1.2) ranged from 3.81 m 2/g OC at lower relative humidities (<63%) to 6.90 m 2/g OC at higher relative humidities (>75%) while sulfate (assumed as ammonium sulfate) efficiencies ranged from 1.23 m 2/g (NH 4) 2SO 4 to 5.78 m 2/g (NH 4) 2SO 4 for the same range of relative humidities. Radiative transfer calculations showed that the rural aerosol at Bondville is most likely to have an overall negative (cooling) forcing effect on climate. Elemental carbon (EC), however, acts to counter sulfate forcing to a degree that has a significant seasonal variation, primarily due to the seasonal variation in the sulfate concentrations. Taking the loading to be the mean summer EC+ammonium sulfate loading and assuming [EC]/[(NH 4) 2SO 4] to be zero in one case (i.e. no soot present) and 0.025 (summer mean at Bondville) in another leads to a 37% difference in calculated forcing.