Abstract

Condensational growth in continuous flow reactors, such as continuously mixed flow reactors (CMFRs) and flow tube reactors, is widely employed in the field of aerosol science and technology to produce particles for industrial use and scientific research. The development of analytical equations for the number-diameter distribution n(d) of the particles in the outflow from these reactors is advantageous both for the inversion of data sets to obtain thermodynamic and kinetic parameters as well as for the rational design of experiments. In this study, equations are derived that relate the number-diameter distribution n(d) to the probability density function p(t) of particle residence time. Specifically, the condensational growth rate is used to derive n(d) based on p(t). Analytical equations are developed for CMFRs, laminar-flow reactors, and dispersive plug-flow reactors, with a focus on CMFRs. The CMFR equation accurately describes data sets collected for α-pinene and β-caryophyllene ozonolysis in the Harva...

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