Abstract

Six different particle size distribution (Gates–Gaudin–Schuhmann (GGS), Rosin–Rammler (RR), Lognormal, Normal, Gamma, and Swebrec) models were compared under different metallurgical coke grinding conditions (ball size and grinding time). Adjusted R2, Akaike information criterion (AIC), and the root mean of square error (RMSE) were employed as comparison criteria. Swebrec and RR presented superior comparison criteria with the higher goodness-of-fit and the lower AIC and RMSE, containing the minimum variance values among data. The worst model fitting was GGS, with the poorest comparison criteria and a wider results variation. The undulation Swebrec parameter was ball size and grinding time-dependent, considering greater b values (b > 3) at longer grinding times. The RR α parameter does not exhibit a defined tendency related to grinding conditions, while the k parameter presents smaller values at longer grinding times. Both models depend on metallurgical coke grinding conditions and are hence an indication of the grinding behaviour. Finally, oversize and ultrafine particles are found with ball sizes of 4.0 cm according to grinding time. The ball size of 2.54 cm shows slight changes in particle median diameter over time, while 3.0 cm ball size requires more grinding time to reduce metallurgical coke particles.

Highlights

  • Metallurgical coke is a crucial raw material in the iron and steelmaking industry and is considered a critical raw material in the EU due to its high consumption volume and the strong EU import dependence [1,2,3]

  • Statistical indexes used in this study, namely adjusted R2, Akaike information criterion (AIC), and root mean of square error (RMSE), have been widely used to the goodness-of-fit assessing of different particle size distribution (PSD) and have presented advantages in the models’ calibration by least-squares method [25,29,32,35]

  • Several PSD models were evaluated on metallurgical coke grinding products using adjusted R2, root means of square error (RMSE) and Akaike’s information criterion (AIC) as statistical indices

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Summary

Introduction

Metallurgical coke is a crucial raw material in the iron and steelmaking industry and is considered a critical raw material in the EU due to its high consumption volume and the strong EU import dependence [1,2,3]. Metallurgical coke is used at different process stages. Coke ranging between 24–40 mm is the main form for blast furnaces; this so-called nut coke is added in ironmaking with ferrous and flux mineral layers from 6 to 24 mm, and coke breeze is considered the energy source for sintering or pelletising with particle size less than 6 mm [6]. Mechanical strength, thermal resistance, and particle size are the most significant parameters for selecting metallurgical coke [6,10]. The coke particle size and shape play an essential role in blast furnace and sinter plants. Coke mean particle size determines the fluid flow resistance, the upward gases and downwards metal liquids passing efficiency, and the iron production rate. The coke bed formation and permeability are strongly related to particle size and combustion behaviour in the sintering process

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