Partially carboxymethylated cotton dust waste for sorption of textile wastewater coloured with the cationic dye Basic Blue 41 as a model: synthesis, regeneration and biodegradability

Abstract

The removal of residual dyes in coloured textile wastewaters is mandatory, and a significant portion of the dyes used are cationic. Textile factories mainly process cotton yarns, and 8 % of this virgin feedstock is lost as cotton dust waste (CDW). Using factorial experimental design, this dust was derivatised with monochloroacetic acid (MCAA) to produce a partially carboxymethylated cellulose (CM−-CDW) with NaOH, MCAA and isopropanol for the retention of Basic Blue 41 dye (BB 41) (column and batch), and biodegradability was investigated. The dye retention efficiency was examined with additional experiments varying the initial concentration, contact time and addition of salts. Heteronuclear multiple bonding correlation-nuclear magnetic resonance confirmed the covalent insertion of CM− groups in the cellulosic fibres. The selected matrix provided a dye sorption of 58.33 (column) and 64.50 mg/g (batch). The Langmuir isotherm was a good fit to the sorption data. The efficiency of uptake of BB 41 was predominantly dictated by the concentration of alkali in the matrix synthesis. Biodegradability by cellulases was similar when using uncharged and dye-charged matrices. The latter were fully regenerated by washing in dilute acid. Retention was proportional to the initial dye concentration and the contact time required to reach equilibrium, which was longer for higher dye concentrations. The addition of 10 mmol/l NaCl decreased BB 41 retention by 50 %. Therefore, CM−-CDW proved effective for the removal of the cationic dye BB 41 and thus represents an important alternative in the treatment of coloured textile effluents.