Abstract
The densities of acetonitrile+water were measured over the whole composition range at 5, 15, 25, 35, and 45 o C. The apparent and partial molar volumes and partial molar expansibilities were evaluated for both components as a function of mole fraction. In the aqueous-rich region, the partial molar volume of acetonitrile increase abruptly with the mole fraction. Only a small minimum of the partial molar volume was observed at very dilute solutions at lower temperatures, althrough a marked maximum was recognized in the partial molar expansibility curve
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