Abstract
The ultrasonic speeds in dilute aqueous solutions of eight alkyl acetates (methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, and tert-butyl acetates) were measured at (5, 15, 25, 35, and 45) °C by means of a sing-around velocimeter. From these data and density results reported previously, the apparent molar isentropic compressions of the alkyl acetates were evaluated. The results were compared with those for more hydrophilic solutes, alcohols reported earlier, and the effects of chain lengthening and chain branching of the alkyl residues on the compression behavior were discussed.
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