Partial inhibition of acrylonitrile–butadiene–styrene dust explosion by sodium bicarbonate

Abstract

During acrylonitrile–butadiene–styrene (ABS) plastic processing, dust explosions could occur in production and transportation. In this paper, the explosion properties and pyrolysis mechanism of ABS dust were studied. The inhibition effects of sodium bicarbonate (NaHCO3) on ABS dust were investigated using the 20-L explosion chamber, Hartmann tube, and G-G furnace. The results demonstrated that NaHCO3 effectively decreased both the ignition sensitivity and the explosion severity of ABS dust explosion by increasing the mass fraction of the inhibitor. Adding 50 wt% NaHCO3 could reduce the explosion hazard to an acceptable level. Combined with an analysis of gas phase products and thermal decomposition behaviour, it was discovered that incorporating NaHCO3 enhanced the heat stability of ABS dust. The decomposition of added NaHCO3 produced a substantial quantity of CO2, consuming many free radicals especially OH• and H•, which further reduced the decomposition temperature of ABS. The inhibitor effectively interrupted the combustion chain reaction and inhibited the propagation of the explosion. The results establish a scientific and operational basis for the prevention and management of dust explosion hazards in the ABS processing field.