Abstract
AbstractThis work deals with some features of the reaction of organic acid chlorides with poly(vinyl alcohol). The structure of the modified polymers was determined by means of IR, UV and NMR spectroscopy as well as by chemical analysis. Vinyl alcohol‐vinyl butyrate copolymers were obtained by reaction of poly(vinyl alcohol) with n‐butyryl chloride without any catalyst. The reaction appeared to satisfy a second order kinetics for conversions no higher than 50%. The activation energy found was of 9.9 kcal/mol. The use of pyridine as a catalyst involved a noticeable increase of the reaction rate, but this effect was found to be independent of the acid chloride used. When triethylamine was used as a catalyst, β‐keto ester groups were found to be grafted onto the polymer chain. The steric hindrance of these groups were thought to be sufficiently important for the conversion to reach a limit of about 30%. The observed swelling in water of vinyl alcohol‐vinyl butyrate copolymers made it reasonable to conclude that the hydrophilic character of the copolymers decreased progressively when the ester group content increased.
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