Abstract

The adsorption of water at 100 K on an ordered film of MgO(100) prepared on Mo(100) is studied by low energy electron diffraction, HREELS (high resolution electron energy loss spectroscopy), and UPS (ultraviolet photoelectron spectroscopy). The appearance of the loss of OH species from HREELS and the 3\ensuremath{\sigma} valence features of the hydroxyl from UPS indicate that the water can be partially dissociated on MgO(100)/Mo(100) at the initial coverages. The experimental results are in good agreement with the theoretical calculations.

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