Abstract
Abstract Partial benzylation of methyl α-d-galactopyranoside with benzyl chloride and LiOH selectively gave the 2,3,6-tribenzyl ether, while that using KOH or RbOH gave the 2,4,6-isomer as the main product. Methyl β-d-galactopyranoside afforded the 3,4,6-tribenzyl ether predominantly, irrespective of the alkali used.
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