Abstract

While nitric oxide (NO) is being monitored in various fields of application, there is still a lack of available instruments at a sub-ppb level of sensitivity. We report on the first application of Optical Feedback Cavity-Enhanced Absorption Spectroscopy (OF-CEAS) to NO trace gas analysis, with a room-temperature quantum-cascade laser at 5.26 µm (1900.5 cm $$^{-1}$$ ). A detection limit of 60 ppt is reached in a single measurement performed in 140 ms. The stability of the instrument allows to average for 10 s down to 8.3 ppt, limited by drift of etalon fringes in the spectra. This work opens the path towards new applications notably in breath analysis and environment sciences.

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