Abstract

A hydrazide-derived bis( meta-phenylene)-32-crown-10 host showed a dimeric structure via quadruple N–H⋯O hydrogen bonds, but a polymeric structure via two N–H⋯O hydrogen bonds and two C–H⋯O hydrogen bonds at each knot in the presence of paraquat in the solid state, which led to a novel poly(taco complex) and ordering arrangement of the guest molecules indirectly.

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