Parameters Affecting the Synthesis of X and A Zeolites from Coal Fly Ash

Abstract

This paper summarizes the investigation results on the main parameters affecting the synthesis of type X and A zeolites using coal silicious fly ash (FA) as raw material. The synthesis was performed by dissolution of alkali-fused alumino-silicates, followed by hydrothermal treatment. The experimental data confirm that fly ash SiO2/Al2O3 ratio, NaOH/FA ratio, acid treatment of pre-fused fly ash, salinity of solution have a significant effect on type and properties of newly formed zeolites. In summary, the results show that A and X-type zeolite form with FA SiO2/Al2O3 ratio < 1.12 and > 1.86, respectively. Moreover, FA characterized by SiO2/Al2O3 mole ratio of 3.15 is suitable for X-type zeolite synthesis while A-type zeolite does not form without NaAlO2 addition. The crystallization occurs faster at higher temperatures although above 90°C X-type zeolite evolves into more stable phases whereas increasing the crystallization time from 1 to 72 hours, the yield of the synthetic products enhances from 60 to 75%. The use of seawater is responsible for the synthesis of X-type showing both lower purity and specific surface area. However, the synthetic products are characterized by high exchange capacity (> 320 meq/100 g), thus suggesting their successful application as adsorbents and catalysts in different types of wastewater and industrial waste treatments.