Abstract
We develop a parameter regression scheme that can be used with battery models of interest to the battery-analysis community. We show that the recent reduced order model (ROM1, 2022 J. Electrochem. 169 070520, DOI: 10.1149/1945–7111/ac7c93), which is based on a perturbation solution, can be used in place of the full system of nonlinear partial differential equations with minimal loss of accuracy for the conditions of this work, which are relevant for electric vehicle applications. The use of the computationally efficient ROM1, cast in the Python programming language, along with a routine native to Python for the nonlinear regression of model parameters through the minimization of the squared differences between experimental results and model calculations, provides a fast method for the overall endeavor. We apply the procedure to examine Ni0.89Co0.05Mn0.05Al0.01O2, a high-capacity material that is of increasing interest with respect to electric vehicles and other products that rely on batteries of high energy density. Difficulties encountered in this work include the large number of parameters governing the battery model, parameter sensitivity in the regression analyses, and the potential for multiple solutions. We close this publication with a discussion of these challenges and open questions with respect to parameter identification.
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