Abstract
triangulo-Trirhenium nonaiodide Re3I9 reacts with 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes) to produce the novel 13-electron paramagnetic cluster Re3I8(IMes)2, which was characterized by means of X-ray diffraction analysis, ESR spectroscopy, magnetometry, and quantum chemistry.
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