Abstract

The EPR line widths of the high and the low field resonances of Cr 3+ in triglycine sulphate (TGS) show two distinct anomalous broadenings near T c . One is associated with a change in the motional frequency of the hindered rotation of the NH 3 groups and the other is related to the fluctuation of the polarization. Just below T c there is a two fold splitting of the resonances which has a (T c −T ) 1 2 temperature dependence indicating the local geometry about the Cr 3+ ion is determined by mean field theory.

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