Abstract

The paramagnetic resonance spectra of Mn 2+ ions in single crystals of CsBr were studied at 9 and 35 GHz. Two different kinds of spectra were observed, which arise from Mn 2+ ions in two different environments; one is a Mn 2+ ion in an aggregated state, and another is a Mn 2+ , which substituted Cs + and is accompanied with a positive ion vacancy in a nearest neighbor cation site. The spin Hamiltonian constants of the spectrum corresponding to the latter were found as g // =1.95±0.02, g ⊥ =2.00±0.02, D =0.390±0.02 cm -1 , A =(90+2)×10 -4 cm -1 .

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