Abstract
One-shot treatment of a mixture of Danishefsky diene 4 and tetraallyltin 8 with 3-formylbenzylidene imines 1 in the presence of Sc(OTf)3 catalyst provides a single product 13 as a result of exclusive Diels–Alder and allylation reactions on the imine and aldehyde functions, respectively. The chemoselectivities of the respective elementary reactions are improved in the parallel reaction, and the redistribution of substrate 1 that is induced readily by Sc(OTf)3 is completely suppressed, thus offering a novel protocol for simplification of the multi-step chemical process.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
