Paper coating performance of hemicellulose-rich natural polymer from distiller's grains

Abstract

• Hemicellulose-based gum from distiller's grains used binder for paper coatings. • Hemicellulose-based gum compared with polyvinyl alcohol as binder. • Paper coated with a formulation consisting of calcium carbonate and binder. • Demonstrated equivalent mechanical and optical properties for coated papers. • Demonstrated potential of gum to replace polyvinyl alcohol for paper coating binder. Coatings contribute to about 10% of the overall cost of paper production of which, the binder is the highest cost component in the formulation. In addition to costs, the binders that are currently being used are synthesized from fossil fuel feedstock raising concerns towards the sustainability of paper coatings. Furthermore, papers coated with waxes, polyolefins and other synthetic materials are difficult to recycle or compost. These challenges inherent with synthetic binders can be addressed by using renewable, plant based binders. This research focused on an abundant and underutilized source of hemicellulose based binders (DG gum) that can be extracted from distiller's dried grains. The extracted binder was compared with polyvinyl alcohol (PVA) in a coating formulation consisting of 10:1 CaCO 3 to binder formulation coated on light weight paper. Cobb test, dry and wet tensile tests, optical properties (brightness, color, opacity), water vapor transmission rate (WVTR) analysis were performed to compare the hemicellulose based binder with PVA. The results indicate water absorptivity reduction by 25% for both DG gum and PVA coatings from the base paper value. Dry tensile index was lower with higher coating weights for both coatings with similar performance. The performance on WVTR analysis for both coatings was also comparable. No significant differences in optical properties after coating were observed from that of the base paper. These results suggest that hemicellulose based binder extracted from distiller's grains has the potential to replace synthetic binders in paper coating formulations.