Abstract

Using 3-aminopropyltriethoxysilan(APTES)to modify the interior surface of SBA-15 channels,PAMAM of generation 1 and generation 2 were successfully grafted in the meso-channels of SBA-15.The PAMAM-SBA-15 hybrids are employed in the adsorption of heavy metal ions to determine their adsorptive capacity,with the APTES modified SBA-15 as a reference sample.The bonding between PAMAM hybrids and metal ions are proved to be much stronger than that of APTES modified SBA-15 by TG-MS tests.Hybrids are used in deposition solution containing several kinds of heavy metal ions, and the selective adsorption of Pb~(2+)and Zn~(2+)is found.After deposition,the concentrations of Pb~(2+) and Zn~(2+)are reduced to 0.003mg/L and 0.037mg/L,respectively,which are lower than the national standard of drinking water.

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