Abstract
Palladium(II) complexes have been found to promote amination of terminal olefins, to give, after reduction, high yields of amines. Internal olefins may also be aminated, but the yields are moderate to low. Cyclohexene and cyclooctene react very sluggishly. In order to avoid formation of bis(amine)palladium complexes, which is a major side reaction, the temperature has to be kept low. Preliminary mechanistic studies show that three moles of amine are required per mole of palladium to ensure good yields.
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