Abstract
The physically stable but chemically reactive square-planar complex (+)-[(dichloro){(S,S)-1,4-dimesyloxy-2,3-butanediamine} palladium(II)] and its platinum(II) analogue have been prepared from the reactions between the dihydrochloride salt of the diamine and K 2MCl 4 (where M=Pd, Pt) in water. The palladium complex has been analysed by X-ray crystallography. In contrast to their metal complexes, the free diamine ligand and its dihydrochloride salt are unstable and cannot be isolated.
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