Abstract

An efficient and concise protocol for the highly regio- and stereoselective synthesis of ferrocene-containing disubstituted E-allylic ester derivatives via a palladium-catalyzed intermolecular arylesterification reaction of ferrocenylallene with aryl iodides and carboxylic acids has been developed. The regio- and stereoselectivities of this reaction may be controlled by the steric effect of the bulky ferrocene group.

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