Abstract
Metathesis of phenylalkyldigermanes (1,2-diphenyltetraethyl-, 1,2-diphenyltetramethyl-, phenylpentaethyl- or phenylpentamethyldigermane) or chloroalkyldigermanes (1,2-dichlorotetraethyl- or 1,2-dichlorotetramethyldigermane) with allylic chlorides proceeds smoothly even at room temperature in the presence of tris(dibenzylideneacetone)dipalladium(0) to afford the corresponding 2-alkenylgermanes in good to high yields.
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