Abstract

AbstractA practical and efficient protocol for the synthesis of biaryl products in good yields by a ligand‐free palladium catalyzed Suzuki–Miyaura reaction of aryl fluorosulfates and various arylboron compounds has been developed. Moreover, we report a one‐pot tandem method for conversion of phenol derivatives to aryl fluorosulfates, and subsequent cross‐coupling to form biaryls.

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