Abstract
This report describes the fluoride-mediated homocoupling of aryl iodides and bromides catalyzed by palladium(0). This coupling protocol is tolerant of electron-donating and electron-withdrawing substitutents on the aryl halide, as well as ortho substitution. Optimum reaction conditions entail 10 mol% Pd(dba) 2, 3 equiv of tetrabutyl ammonium fluoride (TBAF) in DMF at 90 °C.
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