Abstract
The palladium-catalyzed coupling of enolates with aryl and vinyl electrophiles has become a useful method for the construction of carbon–carbon bonds.[1] Although many palladium complexes have been identified that catalyze the coupling of enolates of ketones, esters, amides, and aldehydes with haloarenes, the vinylogous coupling of dienolates of α,β-unsaturated carbonyl compounds with haloarenes (γ-arylation) has been less studied. γ-Aryl α,β-unsaturated carbonyl compounds are useful building blocks because they can be further functionalized at the carbonyl or olefinic positions.[2]
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