Abstract
Von Chlorid zu Boronat: Biarylmonophosphan-Palladium-Katalysatoren zeichnen sich durch hohe Aktivität bei der Borylierung von Aryl- und Heteroarylchloriden aus (siehe Schema). Symmetrische und unsymmetrische Biaryle können auch direkt aus zwei Arylchloriden hergestellt werden, ohne dass die Boronatester-Zwischenprodukte isoliert werden müssen. Rechnungen geben Einblicke in die Rolle des Biarylphosphan-Liganden und der Base KOAc im Katalysezyklus. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2007/z701551_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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