Abstract
AbstractWe report the first introduction of 2‐bromo‐3,3,3‐trifluoropropene (BTP) by directed C–H bond functionalization. The developed method gives straightforward access to α‐(trifluoromethyl)styrene derivatives without prior prefunctionalization of the substrates. This palladium‐catalysed transformation was applied to a broad range of substrates, and the corresponding trifluoromethylated products were obtained in good yields. This approach represents an alternative pathway to the classical method previously used to access such molecules.
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