Palladium Nanoparticles Grown by Using Successive Ionic Layer Adsorption and Reaction Method: Ethanol Electrooxidation and Electrochemical Quartz Crystal Microbalance Studies

Abstract

A facile wet chemical method namely successive ionic layer adsorption and reaction (SILAR) is implemented to grow palladium nanoparticles on graphite substrate. The grown Pd nanoparticles are successfully applied for electrooxidation of ethanol in alkaline solution. The electrocatalytic activity of grown Pd nanoparticles is studied by performing cyclic voltammetry (CV) measurements. Electrooxidation of ethanol by Pd nanoparticles is shown to be affected by growth parameters such as precursor concentration and number of SILAR growth cycles. Excessive growth of Pd nanoparticles due to large number of SILAR growth cycles shifts the pattern of cyclic voltammograms from period-one cyclic voltammograms to high order periodic/aperiodic cyclic voltammograms. Pd nanoparticles are also grown on gold coated quartz crystal and implemented to track any mass changes that occur during electrochemical surface oxidation/reduction over Pd nanoparticles, with and without ethanol in alkaline solution. To measure the mass changes occurring during CV measurements electrochemical quartz crystal microbalance (EQCM) is implemented in situ along with potential scanning.