Abstract

AbstractThe development of high‐efficient electrocatalysts with low applied voltage and robust stability is of great importance for electrolysis of water. In this work, a bifunctional electrode has been developed by growing palladium‐modified FeCoS2 nanosheet arrays on Ni foam (Pd‐FeCoS2 NAs/NF), which can serve as anode and cathode for alkaline water splitting with high activities and ultra‐strong durability. The Pd‐FeCoS2 NAs/NF shows overpotentials of 130 mV for hydrogen evolution reaction (HER) and 202 mV for alkaline oxygen evolution reaction (OER) at 10 mA cm−2. The alkaline electrolyzer is built by employing Pd‐FeCoS2 NAs/NF as cathode and anode, delivering a current density of 50 mA cm−2 at 1.59 V. Moreover, the electrolyzer can run stably for 600 h with negligible decline.

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