Abstract
[PdMe 2(tmeda)] ( 1) reacts with pentafluoropyridine in the presence of water and triethylamine to give the aryloxy compound [PdMe(OC 5NF 4)(tmeda)] ( 2). The structure of 2 has been determined by X-ray crystallography. The palladium oxygen distance to the aryloxy ligand is 2.0368(14) Å. Treatment of 2 with Me 3SiCl effects the cleavage of the palladium oxygen bond and the silane 4-C 5NF 4(OSiMe 3) ( 3) is formed.
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