Abstract
Abstract A Pd/Fe bimetallic catalyst in the presence of the Xantphos ligand promoted the cross-coupling reaction of alcohols and nitroarenes via a hydrogen-transfer redox system. The consecutive formation of aldimines from benzyl alcohols and nitroarenes proceeded in three steps in a single manipulation: oxidation of alcohols, reduction of nitroarenes, and dehydrative condensation of aldehydes and aminoarenes.
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