Abstract
Twelve Pd(II) complexes containing the purine nucleosides adenosine (Ado), guanosine (Guo), inosine (Ino) and xanthosine (Xao) and chloride, bromide or thiocyanate as auxiliary ligands have been isolated and characterized by spectroscopic techniques. Moreover, crystal structures of trans-[Pd(Ino) 2Cl 2]·5H 2O and trans-[Pd(Ino) 2Br 2]·3H 2O have been solved. Both compounds are almost symmetry-centred, which introduces important problems into the solving process. The structure is trans square planar with N(7) coordinated inosine.
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