Abstract
Abstract Moisture and air-stable, robust palladacycle phosphine–ylide complexes as catalyst precursors were used in additive- and amine-free Sonogashira cross-coupling reactions. Various aryl halides were coupled with phenylacetylene in DMF, under air, in the presence of 0.001 mol % of the catalyst to afford the corresponding cross-coupled products in good to excellent yields. Application of the five-membered palladacycle [(P^C)PdCl 2 ] ( C 1 ) in Sonogashira coupling reaction produced comparable catalytic activities of the seven-membered [(C^C)PdCl 2 ] ( C 2 ) analogs.
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