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Abstract
Palladium(II) extraction from nitric acid solutions with 1-{[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-yl]-methyl}-1H-1,2,4-triazole in toluene is studied. The reagent efficiently extracts palladium(II) from 0.2–6 M HNO3 by a coordination mechanism yielding the complex Pd2(NO3)4S3 in the organic phase. The reagent can be used for selective separation of palladium(II) from nickel(II), copper(II), and iron(III) in the specified aqueous phase acidity range.
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