Abstract
Abstract The palladium homobimetallic complexes 2a and 2b with a bridging π-conjugated molecule, N,N′-bis(4′-pyridylmethylidene)-1,4-phenylenediamine (L2a) and 2′-pyridyl derivative L2b, were respectively synthesized and characterized by X-ray crystal structure analysis and cyclic voltammetry. 1H-NMR of 2b indicates the five-coordinate geometry on the palladium center.
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